The first enantiopure lanthanoid cryptate.
نویسندگان
چکیده
The first enantiomerically pure 2,2'-bipyridine-based cryptand is reported. Complexation of this macrobicyclic ligand with the trivalent lanthanoid cations Yb and Lu produces enantiomerically and diastereomerically pure cryptates in solution. The Yb cryptate shows near-IR photoluminescence with lifetimes of up to τ = 29.8 μs in CD3OD.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 11 شماره
صفحات -
تاریخ انتشار 2014